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eMail directory . Software . Web Design . Geologist Consulting Geologist | Home | About me | Contact me | Site Map | Privacy | Security | Standards | Legal | Timothy Casey B.Sc.(Hons.): Consulting Geologist . Not so Apologetic . Deforestation . Climate . Greenhouse Effect . Volcanic CO 2 . Volcanic CFCs . Expanding Earth . Palaeomagnetism . Laser Experiment . The Age of the Earth . Fossil Record. Science . Pseudoscience . Genesis . Interpretation . Movies and Books. Most Misquoted The Shattered Greenhouse: How Simple Physics Demolishes the "Greenhouse Effect". Timothy Casey B.Sc. (Hons.) Consulting Geologist First Uploaded ISO: 2009-Oct-13 Revision 5 ISO: 2011-Dec-07 Some former elements of this article such as the laser experiment, radiation budget commentary, and the UHI implications are to be later reproduced in an additional article concerning the mid-20 th century revival of the "Greenhouse Effect". This notice will be removed when the new article is uploaded. Abstract This article explores the "Greenhouse Effect" in contemporary literature and in the frame of physics, finding a conspicuous lack of clear thermodynamic definition. The "Greenhouse Effect" is defined by Arrhenius’ (1896) modification of Pouillet’s backradiation idea so that instead of being an explanation of how a thermal gradient is maintained at thermal equilibrium, Arrhenius’ incarnation of the backradiation hypothesis offered an extra source of power in addition to the thermally conducted heat which produces the thermal gradient in the material. The general idea as expressed in contemporary literature, though seemingly chaotic in its diversity of emphasis, shows little change since its revision by Svante Arrhenius in 1896, and subsequent refutation by Robert Wood in 1909. The "Greenhouse Effect" is presented as a radiation trap whereby changes in atmospheric composition resulting in increased absorption lead to increased surface temperatures. However, since the composition of a body, isolated from thermal contact by a vacuum, cannot affect mean body temperature, the "Greenhouse Effect" has, in fact, no material foundation. Compositional variation can change the distribution of heat within a body in accordance with Fourier’s Law, but it cannot change the overall temperature of the body. Arrhenius’ Backradiation mechanism did, in fact, duplicate the radiative heat transfer component by adding this component to the conductive heat flow between the earth’s surface and the atmosphere, when thermal conduction includes both contact and radiative modes of heat transfer between bodies in thermal contact. Moreover, the temperature of the earth’s surface and the temperature in a greenhouse are adequately explained by elementary physics. Consequently, the dubious explanation presented by the "Greenhouse Effect" hypothesis is an unnecessary complication. Furthermore, this hypothesis has neither direct experimental confirmation nor direct empirical evidence of a material nature. Thus the notion of "Anthropogenic Global Warming", which rests on the "Greenhouse Effect", also has no real foundation. 1.0 Introduction: What on Earth Is the "Greenhouse Effect"? Confusion and Lack of Thermodynamic Definition Although the "Greenhouse Effect" is of crucial importance to modern climatology and is the putative cornerstone of the Anthropogenic Global Warming hypothesis, it lacks clear thermodynamic definition. This forecasts the likelihood that the name is misapplied. Even general descriptions of the "Greenhouse Effect" may seem confused when compared to one another. In the first year university geology text by Press & Siever (1982, p. 312) we read: "The atmosphere is relatively transparent to the incoming visible rays of the Sun. Much of that radiation is absorbed at the Earth’s surface and then reemitted as infrared, invisible long-wave rays that radiate back away from the surface (Fig. 12-14). The atmosphere, however, is relatively opaque and impermeable to infrared rays because of the combined effect of clouds and carbon dioxide, which strongly absorbs the radiation instead of allowing it to escape into space. This absorbed radiation heats the atmosphere, which radiates heat back to the Earth’s surface. This is called the ’greenhouse effect’ by analogy to the warming of greenhouses, whose glass is the barrier to heat loss." This explanation is fundamentally confusing because it is seemingly contradictory, as impermeable materials cannot absorb on the minute to minute timescale that applies to the "Greenhouse Effect", even if such an impermeable material has a very high fluid storage capacity or porosity. According to Press & Siever’s explanation above, the atmosphere is relatively impermeable due to the presence of clouds and carbon dioxide, which are part of the atmosphere. How then, can the part of the atmosphere that makes it impermeable to infrared, simultaneously facilitate infrared absorption? Moreover, the idea of thermal permeability is a product of the 19 th century pseudoscientific notion that heat was actually a fluid (called "caloric"). This led to a great deal of misunderstanding amongst the scientifically illiterate when it came to the findings of Fourier (e.g. Kelland, 1837). We may compare this description of the "Greenhouse Effect" with that of Whitaker (2007, pp. 17-18), which lacks the misplaced 19 th century usage: "The incoming solar radiation that the earth absorbs is re-emitted in the form of so-called infra-red radiation - this is where the vital ’greenhouse effect’ begins. Because of the chemical structure of the greenhouse gases in the atmosphere, they absorb the infra-red radiation from the Earth, and then emit it, into space and back into the atmosphere. The atmospheric re-emission helps heat the surface of the Earth - as well as the lower atmosphere - and keeps us warm." This explanation describes the "Greenhouse Effect" as "vital", perhaps because, as Whitaker points out, it warms the earth’s surface. Wishart (2009, p. 24) explains that this "Greenhouse Effect" is useful for a completely different reason: "The Moon is another excellent example of what happens with no greenhouse effect. During the lunar day, average surface temperatures reach 107ºC, while the lunar night sees temperatures drop from boiling point to 153 degrees below zero. No greenhouse gases mean there’s no way to smooth out temperatures on the moon. On Earth, greenhouse gases filter some of the sunlight hitting the surface and reflect some of the heat back out into space, meaning the days are cooler, but conversely the gases insulate the planet at night, preventing a lot of the heat from escaping." In Wishart’s explanation above, the Greenhouse Effect" is no longer a warming mechanism but a thermal buffer that moderates the extremes of temperature. In fact, Plimer (2001) uses the term "greenhouse" to denote interglacial periods (e.g. Plimer, 2001, p. 80). In describing the conditions when life evolved on earth 3800 million years ago, Plimer (2001, p. 43), like Wishart, is more reminiscent of Frankland (1864) and Tyndall (1867): "The Earth’s temperature had moderated because the atmosphere was rich in carbon dioxide and water vapour created a greenhouse." The above quotes demonstrate a confusing array of "Greenhouse Effect" definitions, including the first one which seems to contradict itself. Plimer (2009, p. 365) really describes this situation very well when he writes: "Everyone knows what the greenhouse effect is. Well ... do they? Ask someone to explain how the greenhouse effect works. There is an extremely high probability that they have no idea. What really is the greenhouse effect? The use of the term ’greenhouse effect’ is a complete misnomer. Greenhouses or glasshouses are used for increasing plant growth, especially in colder climates. A greenhouse eliminates convective cooling, the major process of heat transfer in the atmosphere, and protects the plants from frost." The "Greenhouse...

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